Diffusion-based Assay:Article Title: Solvation sheath reorganization enables fast ion transfer kinetics in lithium-ion battery.
Article Snippet: Characterization The solvation structures of different electrolytes were measured by 7Li coaxial nuclear magnetic resonance spectroscopy (NMR) (Bruker 600MHz), Raman spectrum (Horiba LabRAM HR Evolution) and electrical in-situ Fourier-transform infrared spectroscopy (FTIR) (Thermo IS50). .. The self-diffusion coefficients of different electrolytes were measured by 1H, 7Li and 19F diffusion ordered spectroscopy (DOSY) NMR (Bruker 600MHz). .. The positive electrodes and negative electrodes were disassembled from graphite||NMC811 full cells cycled 100 cycles and rinsed with anhydrous DMC three times to remove the residuals (inside the glovebox), followed by characterizations of scanning electron microscopy (SEM) (SU-70, Hitachi Ltd.), transmission electron microscopy (TEM) (Tecnai G2 F20), X-ray photoelectron spectroscopy (XPS) (Thermo Scientific ESCALAB 250Xi) with a sputtering rate of 0.02 nm s-1 and time of flight secondary ion mass spectrometry (TOF-SIMS) (ToF.SIMS 5-100 instrument IONTOF GmbH).
Article Title: Mechanochemically accelerated deconstruction of chemically recyclable plastics
Article Snippet: .. Self-diffusion coefficients were measured using pulsed field gradient (PFG) NMR at a field strength of 9.4 T on a Bruker NEO 400 MHz spectrometer fitted with a 5 mm water cooled double resonance broad band diffusion (diffBB) probe equipped with z-axis gradient and a variable temperature unit that was maintained at 25°C throughout measurements. .. Self-diffusion coefficients were measured using pulsed field gradient (PFG) NMR at a field strength of 9.4 T on a Bruker NEO 400 MHz spectrometer fitted with a 5 mm water cooled double resonance broad band diffusion (diffBB) probe equipped with z-axis gradient and a variable temperature unit that was maintained at 25°C throughout measurements.
Article Title: Solvation sheath reorganization enables fast ion transfer kinetics in lithium-ion battery.
Article Snippet: Characterization The solvation structures of different electrolytes were measured by Li coaxial nuclear magnetic resonance spectroscopy (NMR) (Bruker 600MHz), Raman spectrum (Horiba LabRAM HR Evolution) and electrical in-situ Fourier-transform infrared spectroscopy (FTIR) (Thermo IS50). .. The self-diffusion coefficients of different electrolytes were measured by H, Li and F diffusion ordered spectroscopy (DOSY) NMR (Bruker 600MHz). .. The positive electrodes and negative electrodes were disassembled from graphite||NMC811 full cells cycled 100 cycles and rinsed with anhydrous DMC three times to remove the residuals (inside the glovebox), followed by characterizations of scanning electron microscopy (SEM) (SU-70, Hitachi Ltd.), transmission electron microscopy (TEM) (Tecnai G2 F20), X-ray photoelectron spectroscopy (XPS) (Thermo Scientific ESCALAB 250Xi) with a sputtering rate of 0.02 nm s and time of flight secondary ion mass spectrometry (TOF-SIMS) (ToF.SIMS 5-100 instrument IONTOF GmbH).
Article Title: Structural and dynamical heterogeneities at the nanoscale in alkali/earth alkaline ionic liquid electrolytes: experiment and molecular simulation.
Article Snippet: .. Self-diffusion coefficients were measured by pulsed-field gradient nuclear magnetic resonance (PFG-NMR) using a Bruker 400 Avance III HD spectrometer (frequencies are 400.13, 376.50 and 155.51 MHz for 1H, 19F and 7Li, respectively) and a Bruker 300 Avance III spectrometers for 133Cs PFG-NMR (frequency: 39.35 MHz), both equipped with 5 mm diffusion probe and temperature regulation unit (20–80 1C, accuracy and stability 2 1C). .. Self-diffusion coefficients were measured by pulsed-field gradient nuclear magnetic resonance (PFG-NMR) using a Bruker 400 Avance III HD spectrometer (frequencies are 400.13, 376.50 and 155.51 MHz for 1H, 19F and 7Li, respectively) and a Bruker 300 Avance III spectrometers for 133Cs PFG-NMR (frequency: 39.35 MHz), both equipped with 5 mm diffusion probe and temperature regulation unit (20–80 1C, accuracy and stability 2 1C).
Spectroscopy:Article Title: Solvation sheath reorganization enables fast ion transfer kinetics in lithium-ion battery.
Article Snippet: Characterization The solvation structures of different electrolytes were measured by 7Li coaxial nuclear magnetic resonance spectroscopy (NMR) (Bruker 600MHz), Raman spectrum (Horiba LabRAM HR Evolution) and electrical in-situ Fourier-transform infrared spectroscopy (FTIR) (Thermo IS50). .. The self-diffusion coefficients of different electrolytes were measured by 1H, 7Li and 19F diffusion ordered spectroscopy (DOSY) NMR (Bruker 600MHz). .. The positive electrodes and negative electrodes were disassembled from graphite||NMC811 full cells cycled 100 cycles and rinsed with anhydrous DMC three times to remove the residuals (inside the glovebox), followed by characterizations of scanning electron microscopy (SEM) (SU-70, Hitachi Ltd.), transmission electron microscopy (TEM) (Tecnai G2 F20), X-ray photoelectron spectroscopy (XPS) (Thermo Scientific ESCALAB 250Xi) with a sputtering rate of 0.02 nm s-1 and time of flight secondary ion mass spectrometry (TOF-SIMS) (ToF.SIMS 5-100 instrument IONTOF GmbH).
Article Title: Solvation sheath reorganization enables fast ion transfer kinetics in lithium-ion battery.
Article Snippet: Characterization The solvation structures of different electrolytes were measured by Li coaxial nuclear magnetic resonance spectroscopy (NMR) (Bruker 600MHz), Raman spectrum (Horiba LabRAM HR Evolution) and electrical in-situ Fourier-transform infrared spectroscopy (FTIR) (Thermo IS50). .. The self-diffusion coefficients of different electrolytes were measured by H, Li and F diffusion ordered spectroscopy (DOSY) NMR (Bruker 600MHz). .. The positive electrodes and negative electrodes were disassembled from graphite||NMC811 full cells cycled 100 cycles and rinsed with anhydrous DMC three times to remove the residuals (inside the glovebox), followed by characterizations of scanning electron microscopy (SEM) (SU-70, Hitachi Ltd.), transmission electron microscopy (TEM) (Tecnai G2 F20), X-ray photoelectron spectroscopy (XPS) (Thermo Scientific ESCALAB 250Xi) with a sputtering rate of 0.02 nm s and time of flight secondary ion mass spectrometry (TOF-SIMS) (ToF.SIMS 5-100 instrument IONTOF GmbH).
Article Title: Poly(Ionic Liquid) Electrolytes at an Extreme Salt Concentration for Solid-State Batteries.
Article Snippet: Self-diffusion coefficients of ionic species were studied using PFG NMR spectroscopy on a Bruker Avance III 300 MHz wide bore spectrometer equipped with Diff50 pulse field gradient probe at 80 °C. .. Self-diffusion coefficients of ionic species were studied using PFG NMR spectroscopy on a Bruker Avance III 300 MHz wide bore spectrometer equipped with Diff50 pulse field gradient probe at 80 °C. ..
Nuclear Magnetic Resonance:Article Title: Solvation sheath reorganization enables fast ion transfer kinetics in lithium-ion battery.
Article Snippet: Characterization The solvation structures of different electrolytes were measured by 7Li coaxial nuclear magnetic resonance spectroscopy (NMR) (Bruker 600MHz), Raman spectrum (Horiba LabRAM HR Evolution) and electrical in-situ Fourier-transform infrared spectroscopy (FTIR) (Thermo IS50). .. The self-diffusion coefficients of different electrolytes were measured by 1H, 7Li and 19F diffusion ordered spectroscopy (DOSY) NMR (Bruker 600MHz). .. The positive electrodes and negative electrodes were disassembled from graphite||NMC811 full cells cycled 100 cycles and rinsed with anhydrous DMC three times to remove the residuals (inside the glovebox), followed by characterizations of scanning electron microscopy (SEM) (SU-70, Hitachi Ltd.), transmission electron microscopy (TEM) (Tecnai G2 F20), X-ray photoelectron spectroscopy (XPS) (Thermo Scientific ESCALAB 250Xi) with a sputtering rate of 0.02 nm s-1 and time of flight secondary ion mass spectrometry (TOF-SIMS) (ToF.SIMS 5-100 instrument IONTOF GmbH).
Article Title: Mechanochemically accelerated deconstruction of chemically recyclable plastics
Article Snippet: .. Self-diffusion coefficients were measured using pulsed field gradient (PFG) NMR at a field strength of 9.4 T on a Bruker NEO 400 MHz spectrometer fitted with a 5 mm water cooled double resonance broad band diffusion (diffBB) probe equipped with z-axis gradient and a variable temperature unit that was maintained at 25°C throughout measurements. .. Self-diffusion coefficients were measured using pulsed field gradient (PFG) NMR at a field strength of 9.4 T on a Bruker NEO 400 MHz spectrometer fitted with a 5 mm water cooled double resonance broad band diffusion (diffBB) probe equipped with z-axis gradient and a variable temperature unit that was maintained at 25°C throughout measurements.
Article Title: Solvation sheath reorganization enables fast ion transfer kinetics in lithium-ion battery.
Article Snippet: Characterization The solvation structures of different electrolytes were measured by Li coaxial nuclear magnetic resonance spectroscopy (NMR) (Bruker 600MHz), Raman spectrum (Horiba LabRAM HR Evolution) and electrical in-situ Fourier-transform infrared spectroscopy (FTIR) (Thermo IS50). .. The self-diffusion coefficients of different electrolytes were measured by H, Li and F diffusion ordered spectroscopy (DOSY) NMR (Bruker 600MHz). .. The positive electrodes and negative electrodes were disassembled from graphite||NMC811 full cells cycled 100 cycles and rinsed with anhydrous DMC three times to remove the residuals (inside the glovebox), followed by characterizations of scanning electron microscopy (SEM) (SU-70, Hitachi Ltd.), transmission electron microscopy (TEM) (Tecnai G2 F20), X-ray photoelectron spectroscopy (XPS) (Thermo Scientific ESCALAB 250Xi) with a sputtering rate of 0.02 nm s and time of flight secondary ion mass spectrometry (TOF-SIMS) (ToF.SIMS 5-100 instrument IONTOF GmbH).
Article Title: Poly(Ionic Liquid) Electrolytes at an Extreme Salt Concentration for Solid-State Batteries.
Article Snippet: Self-diffusion coefficients of ionic species were studied using PFG NMR spectroscopy on a Bruker Avance III 300 MHz wide bore spectrometer equipped with Diff50 pulse field gradient probe at 80 °C. .. Self-diffusion coefficients of ionic species were studied using PFG NMR spectroscopy on a Bruker Avance III 300 MHz wide bore spectrometer equipped with Diff50 pulse field gradient probe at 80 °C. ..
Article Title: Dynamics of fluorinated imide-based ionic liquids using nuclear magnetic resonance techniques.
Article Snippet: There is increasing interest in studying molecular motions in ionic liquids to gain better insights into their transport properties and to expand their applications.. In this study, we have employed the fast field cycling relaxometry and pulsed field gradient nuclear magnetic resonance techniques to investigate the rotational and translational dynamics of fluorinated imide-based ionic liquids (ILs) at different temperatures.. We have studied a total of six ILs composed of the 1-butyl-3-methylimidazolium cation ([BMIM]) combined with chemically modified analogs of the bis((trifluoromethyl)sulfonyl)imide anion ([NTf2] or [TFSI] ).
Article Title: Structural and dynamical heterogeneities at the nanoscale in alkali/earth alkaline ionic liquid electrolytes: experiment and molecular simulation.
Article Snippet: .. Self-diffusion coefficients were measured by pulsed-field gradient nuclear magnetic resonance (PFG-NMR) using a Bruker 400 Avance III HD spectrometer (frequencies are 400.13, 376.50 and 155.51 MHz for 1H, 19F and 7Li, respectively) and a Bruker 300 Avance III spectrometers for 133Cs PFG-NMR (frequency: 39.35 MHz), both equipped with 5 mm diffusion probe and temperature regulation unit (20–80 1C, accuracy and stability 2 1C). .. Self-diffusion coefficients were measured by pulsed-field gradient nuclear magnetic resonance (PFG-NMR) using a Bruker 400 Avance III HD spectrometer (frequencies are 400.13, 376.50 and 155.51 MHz for 1H, 19F and 7Li, respectively) and a Bruker 300 Avance III spectrometers for 133Cs PFG-NMR (frequency: 39.35 MHz), both equipped with 5 mm diffusion probe and temperature regulation unit (20–80 1C, accuracy and stability 2 1C).
other:Article Title: Viridium: A Stable Radical and Its π-Dimerization.
Article Snippet: Nuclear magnetic resonance (NMR) spectra for 1H were acquired on Bruker AVANCE 300, 400, 500 and 600 spectrometers.
Sequencing:Article Title: Dynamics of fluorinated imide-based ionic liquids using nuclear magnetic resonance techniques.
Article Snippet: There is increasing interest in studying molecular motions in ionic liquids to gain better insights into their transport properties and to expand their applications.. In this study, we have employed the fast field cycling relaxometry and pulsed field gradient nuclear magnetic resonance techniques to investigate the rotational and translational dynamics of fluorinated imide-based ionic liquids (ILs) at different temperatures.. We have studied a total of six ILs composed of the 1-butyl-3-methylimidazolium cation ([BMIM]) combined with chemically modified analogs of the bis((trifluoromethyl)sulfonyl)imide anion ([NTf2] or [TFSI] ).
Temperature Regulation:Article Title: Structural and dynamical heterogeneities at the nanoscale in alkali/earth alkaline ionic liquid electrolytes: experiment and molecular simulation.
Article Snippet: .. Self-diffusion coefficients were measured by pulsed-field gradient nuclear magnetic resonance (PFG-NMR) using a Bruker 400 Avance III HD spectrometer (frequencies are 400.13, 376.50 and 155.51 MHz for 1H, 19F and 7Li, respectively) and a Bruker 300 Avance III spectrometers for 133Cs PFG-NMR (frequency: 39.35 MHz), both equipped with 5 mm diffusion probe and temperature regulation unit (20–80 1C, accuracy and stability 2 1C). .. Self-diffusion coefficients were measured by pulsed-field gradient nuclear magnetic resonance (PFG-NMR) using a Bruker 400 Avance III HD spectrometer (frequencies are 400.13, 376.50 and 155.51 MHz for 1H, 19F and 7Li, respectively) and a Bruker 300 Avance III spectrometers for 133Cs PFG-NMR (frequency: 39.35 MHz), both equipped with 5 mm diffusion probe and temperature regulation unit (20–80 1C, accuracy and stability 2 1C).
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